Temperature fluctuations significantly impact the lifespan of energy storage cells. Higher operating temperatures generally increase the rate of chemical degradation within the
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Temperature fluctuations significantly impact the lifespan of energy storage cells. Higher operating temperatures generally increase the rate of chemical degradation within the battery, leading to accelerated
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(A) Capacity change with cycle number of batteries cycling at C/5 rate at 85 °C and 120 °C, respectively. B1 cells: After two initial cycles at 60 °C, the cells were cycled at 85 °C between 2.7 V and 4.1 V for 15 days; B2 cells: After two initial cycles at 60 °C, the cells were cycled at 120 °C between 2.7 V and 4.1 V for 15 days.
From the perspective of the battery, the thermal behaviour of lithium-based batteries depends considerably on their underlying chemistry. Lithium iron phosphate cells typically demonstrate a higher thermal stability and lower susceptibility to thermal runaway, albeit at the expense of lower energy density.
In addition to thermal management strategies, improving the thermal stability and flame retardancy of internal battery materials is a critical approach to enhancing the thermal safety of batteries. In terms of fire prevention, cooling sprays have proven to be effective.
Also, sensors to monitor the temperature fluctuations, stress changes and gas generation can also be embedded in the battery system to monitor the thermal process of the battery system.
Operating within a suitable temperature range keeps the main reversible chemical reactions of the battery in a stable equilibrium, while side reactions (such as electrolyte decomposition or electrode material breakdown), which require higher activation energy, are inhibited 118.
However, there are no battery materials or systems that can be deemed absolutely safe or performance-temperature-independent. In this Perspective, we discuss battery safety from a thermal point of view and emphasize the importance of battery thermal management.
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